[Pt1Ag37(SAdm)21(Dppp)3Cl6]2+: intercluster transformation and photochemical properties-Reference-Cited by-同舟云学术

[Pt₁Ag₃₇(SAdm)₂₁(Dppp)₃Cl₆]²⁺: intercluster transformation and photochemical properties

Published:2022 Issue:15 Volume:9 Page:3907-3914
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhen Yaru¹²,Jin Shan³^ORCID,Kang Xi¹²^ORCID,Xu Chang¹^ORCID,Fang Cao¹²,Hu Daqiao¹²^ORCID,Zhu Manzhou¹²^ORCID

Affiliation:

1. Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei 230601, P. R. China

2. Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, P. R. China

3. Institutes of Physical Science and Information Technology, Anhui University, Hefei 230601, P. R. China

Abstract

A novel [Pt1Ag37(SAdm)21(Dppp)3Cl6]2+ nanocluster is reported, and the reaction with PPh3 triggers an intercluster transformation into [Pt1Ag28(SAdm)18(PPh3)4]2+. Using chiral Bdpp, the enantiomeric Pt1Ag37(SAdm)21(R/S-Bdpp)3Cl6 can be prepared.

Funder

Ministry of Education of the People's Republic of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI01082H

Reference59 articles.

1. Toward Active-Site Tailoring in Heterogeneous Catalysis by Atomically Precise Metal Nanoclusters with Crystallographic Structures

2. Surface Chemistry of Atomically Precise Coinage–Metal Nanoclusters: From Structural Control to Surface Reactivity and Catalysis