Indium-catalysed amide allylation of α-iminoamide: highly enantioselective synthesis of amide functionalised α-methylene-γ-butyrolactams
Author:
Affiliation:
1. Department of Applied Chemistry
2. Faculty of Engineering
3. Shizuoka University
4. Hamamatsu 432-8561
5. Japan
6. Department of Applied Chemistry and Biotechnology
7. Graduate School of Engineering
8. Chiba University
9. Chiba 263-8522
Abstract
A highly enantioselective amide allylation of α-iminoamides has been achieved using catalytic amounts of InCl3, ZnCl2 and a BINOL derivative.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C6OB02506D
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5. Catalytic asymmetric allylation of carbonyl compounds and imines with allylic boronates
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