Controlling factors of oligomerization at the water surface: why is isoprene such a unique VOC?

Author:

Ishizuka Shinnosuke12345ORCID,Fujii Tomihide6784,Matsugi Akira910114ORCID,Sakamoto Yosuke678412ORCID,Hama Tetsuya1234ORCID,Enami Shinichi5134ORCID

Affiliation:

1. Institute of Low Temperature Science

2. Hokkaido University

3. Sapporo 060-0819

4. Japan

5. National Institute for Environmental Studies

6. Graduate School of Global Environmental Studies

7. Kyoto University

8. Kyoto 606-8501

9. Research Institute of Science for Safety and Sustainability

10. National Institute of Advanced Industrial Science and Technology

11. Tsukuba 305-8569

12. Graduate School of Human and Environmental Studies

13. Tsukuba 305-8506

Abstract

The interfacial oligomerization of isoprene is facilitated by the resonance stabilization through the formation of a tertiary carbocation with a conjugated CC bond pair, and electron enrichment induced by the neighboring methyl group.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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3. Hydronium Ion Acidity Above and Below the Interface of Aqueous Microdroplets;ACS Earth and Space Chemistry;2021-08-25

4. Aqueous Microdroplets Capture Elusive Carbocations;Journal of the American Chemical Society;2021-02-03

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