An additional potential donor-bearing alkylidene-containing latent NHC–ruthenium-based catalyst for olefin metathesis polymerization

Author:

Sivanesan Dharmalingam12345,Seo Bongkuk12345,Lim Choong-Sun12345ORCID,Choi Dongchen12345,Kim Taehee12345,Kim Hyeon-Gook12345ORCID

Affiliation:

1. Advanced Industrial Chemistry Research Center

2. Advanced Convergent Chemistry Division

3. Korea Research Institute of Chemical Technology (KRICT)

4. Ulsan

5. 44412 Korea

Abstract

Introduction of an additional donor, by tethering substituted pyridine, in the alkylidene ligand of a NHC-based ruthenium complex initiates latent olefin metathesis polymerization.

Funder

Korea Research Institute of Chemical Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference42 articles.

1. R. H. Grubbs and S. H.Pine , in Comprehensive Organic Synthesis , ed. B. M. Trost , I. Fleming and L. A. Paquette , Pergamon , New York , 1991 , ch. 9.3, vol. 5

2. K. J. Ivin and J. C.Mol , Olefin Metathesis and Metathesis Polymerization , Academic Press , San Diego, CA , 1997

3. The development of well-defined catalysts for ring-opening olefin metathesis polymerizations (ROMP)

4. Ring-Closing Metathesis and Related Processes in Organic Synthesis

5. (PCy3)2Cl2RuCHR: An Efficient and Selective Reagent for the formation of CC-double bonds by non-polymerizing metathesis reactions

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