Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

Author:

Petrov Pavel A.12342ORCID,Naumov Dmitry Yu.123,Sukhikh Taisiya S.12342ORCID,Konchenko Sergey N.12342,Gómez-García Carlos J.56789,Llusar Rosa1011129ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS

2. 630090 Novosibirsk

3. Russian Federation

4. Novosibirsk State University

5. Instituto de Ciencia Molecular (ICMol)

6. C/Catedrático José Beltrán, 2

7. Universidad de Valencia

8. 46980 Paterna (Valencia)

9. Spain

10. Departament de Química Física i Analítica

11. Universitat Jaume I

12. 12071 Castelló

Abstract

The paramagnetic cuboidal clusters [Mo3(GaBr)(μ3-S)4(diphos)3Br3] (diphos = dppe, dmpe) were synthesized by the reduction of triangular clusters [Mo3S4(diphos)3Br3]Br with elemental Ga.

Funder

German Academic Exchange Service

Russian Foundation for Basic Research

Generalitat Valenciana

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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