Rotational spectra of tetracyclic quinolizidine alkaloids: does a water molecule flip sparteine?-Reference-Cited by-同舟云学术

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Rotational spectra of tetracyclic quinolizidine alkaloids: does a water molecule flip sparteine?

Published:2017 Issue:27 Volume:19 Page:17553-17559
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lesarri Alberto¹²³⁴⁵^ORCID,Pinacho Ruth⁶⁷³⁴⁵^ORCID,Enríquez Lourdes⁶⁷³⁴⁵^ORCID,Rubio José E.⁶⁷³⁴⁵^ORCID,Jaraíz Martín⁶⁷³⁴⁵^ORCID,Abad José L.⁸⁹¹⁰¹¹¹²^ORCID,Gigosos Marco A.¹³¹⁴²³⁴^ORCID

Affiliation:

1. Departamento de Química Física y Química Inorgánica

2. Facultad de Ciencias

3. Universidad de Valladolid

4. 47011 Valladolid

5. Spain

6. Departamento de Electrónica

7. Escuela de Ingeniería de Telecomunicaciones

8. Spanish National Research Council (CSIC)

9. Institute of Advanced Chemistry of Catalonia (IQAC-CSIC)

10. Research Unit on Bioactive Molecules (RUBAM)

11. Department of Biomedicinal Chemistry

12. 08034 Barcelona

13. Departamento de Física Teórica

14. Atómica y Óptica

Abstract

Flipping or not flipping? The sparteine–water dimer generated in a jet expansion retains the trans conformation of the parent molecule.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01432E

Reference54 articles.

1. N. J. Leonard , in The Alkaloids, Chemistry and Physiology, ed. R. H. F. Manske and H. L. Holmes, Academic Press, New York, vol. III, 1953

2. T. Aniszewski , Alkaloids, Chemistry, Biology, Ecology and Applications, Elsevier, Amsterdam, 2nd edn, 2015

3. The Total Synthesis of Sparteine and an Isosparteine by Reductive Cyclization1

4. A stereoselective synthesis of α-isosparteine

5. Biosynthesis of the lupine alkaloids. II. Sparteine and lupanine

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3. Molecular Rotation Spectrum of Tetracyclic Quinolizidines: Observation of trans-Matrine and the Elusive cis-Matrine;The Journal of Organic Chemistry;2021-01-06

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