Synthesis and characterization of a novel aminopolycarboxylate complexant for efficient trivalent f-element differentiation: N-butyl-2-acetamide-diethylenetriamine-N,N′,N′′,N′′-tetraacetic acid-Reference-Cited by-同舟云学术

Synthesis and characterization of a novel aminopolycarboxylate complexant for efficient trivalent f-element differentiation: N-butyl-2-acetamide-diethylenetriamine-N,N′,N′′,N′′-tetraacetic acid

Published:2018 Issue:4 Volume:47 Page:1092-1105
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Heathman Colt R.¹²³⁴^ORCID,Grimes Travis S.¹²³⁴^ORCID,Jansone-Popova Santa⁵⁶⁷⁴^ORCID,Ivanov Alexander S.⁵⁶⁷⁴^ORCID,Bryantsev Vyacheslav S.⁵⁶⁷⁴^ORCID,Zalupski Peter R.¹²³⁴^ORCID

Affiliation:

1. Aqueous Separations and Radiochemistry

2. Idaho National Laboratory

3. Idaho Falls

4. USA

5. Chemical Sciences Division

6. Oak Ridge National Laboratory

7. Oak Ridge

Abstract

Novel aminopolycarboxylate complexant N-butyl-2-acetamide-diethylenetriamine-N,N′,N′′,N′′-tetraacetic acid was synthesized to discriminate trivalent actinides from trivalent lanthanides in aqueous mixtures of unconventional acidity.

Funder

Office of Science

Office of Nuclear Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04104G

Reference71 articles.

1. 835. Separation of the lanthanons by ion exchange. A comparison of eluants

2. The Separation of Adjacent Rare Earths with Ethylenediamine-tetraacetic Acid by Elution from an Ion-exchange Resin1