Unveiling the role of ancillary ligands in acceptorless benzyl alcohol dehydrogenation and etherification mediated by mesoionic carbene iridium complexes

Author:

Vivancos Ángela12345ORCID,Petronilho Ana5678,Cardoso Joao5678,Müller-Bunz Helge5678,Albrecht Martin12345ORCID

Affiliation:

1. Departement für Chemie und Biochemie

2. Universität Bern

3. CH-3012 Bern

4. Switzerland

5. School of Chemistry & Chemical Biology

6. University College Dublin

7. Dublin 4

8. Ireland

Abstract

We synthesized a set of triazolylidene iridium(iii) complexes [IrCp*(C^N)L]n+ containing different neutral or anionic ancillary ligands L and demonstrated their impact on the catalytic activity in alcohol conversion.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

FP7 Ideas: European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

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2. M. Nielsen , Hydrogen Production by Homogeneous Catalysis: Alcohol Acceptorless Dehydrogenation , in Hydrogen Production and Remediation of Carbon and Pollutants , ed. E. Lichtfouse , J. Schwarzbauer and D. Robert , Springer , Heidelberg , 2015

3. Modern Oxidation Methods , ed. J.-E. Bäckvall , Wiley-VCH , Weinheim, Germany , 2008

4. The Handbook of Homogeneous Hydrogenation , ed. J. G. De Vries and C. J. Elsevier , Wiley-VCH , Weinheim, Germany , 2008

5. Stable Carbenes

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