Transition-metal free alkylarylation of acrylamides initiated by radical C–C bond cleavage of the tertiary cycloalkanols
Author:
Affiliation:
1. Department of Chemistry
2. School of Science and MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter
3. Xi'an Jiaotong University
4. Xi'an 710049
5. China
6. Xi'an Libang Pharmaceutical Co., LTD
Abstract
An efficient Na2S2O8-promoted radical cyclization reaction of acrylamides with the tertiary cycloalkanols has been developed. This one pot procedure involves a tandem C–C bond cleavage and two C–C bonds formation process.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA03431D
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