Transition-metal free alkylarylation of acrylamides initiated by radical C–C bond cleavage of the tertiary cycloalkanols-Reference-Cited by-同舟云学术

Transition-metal free alkylarylation of acrylamides initiated by radical C–C bond cleavage of the tertiary cycloalkanols

Published:2016 Issue:32 Volume:6 Page:27000-27003
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Guo Li-Na¹²³⁴⁵,Deng Zhi-Qiang¹²³⁴⁵,Wu Yong¹²³⁴⁵,Hu Jie⁶⁵

Affiliation:

1. Department of Chemistry

2. School of Science and MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter

3. Xi'an Jiaotong University

4. Xi'an 710049

5. China

6. Xi'an Libang Pharmaceutical Co., LTD

Abstract

An efficient Na₂S₂O₈-promoted radical cyclization reaction of acrylamides with the tertiary cycloalkanols has been developed. This one pot procedure involves a tandem C–C bond cleavage and two C–C bonds formation process.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA03431D

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4. Metal-free carbonitration of alkenes using K2S2O8

5. Metal-free oxidative arylphosphination of activated N-substituted-N-arylacrylamide derivatives using K2S2O8

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