Transition-metal free alkylarylation of acrylamides initiated by radical C–C bond cleavage of the tertiary cycloalkanols

Author:

Guo Li-Na12345,Deng Zhi-Qiang12345,Wu Yong12345,Hu Jie65

Affiliation:

1. Department of Chemistry

2. School of Science and MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter

3. Xi'an Jiaotong University

4. Xi'an 710049

5. China

6. Xi'an Libang Pharmaceutical Co., LTD

Abstract

An efficient Na2S2O8-promoted radical cyclization reaction of acrylamides with the tertiary cycloalkanols has been developed. This one pot procedure involves a tandem C–C bond cleavage and two C–C bonds formation process.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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