Supramolecular control of monooxygenase reactivity in a copper(ii) cryptate
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. Concordia University
3. Montreal
4. Canada
5. Équipe de Chimie Inorganique Redox
6. Département de Chimie Moléculaire
7. Université Joseph Fourier
8. Cedex 9
9. France
Abstract
We report on the formation and self-decomposition of Cu(ii)–hydroperoxo intermediates with a cryptand ligand. The second coordination sphere of the cryptand steers the oxidative reactivity of the intermediates towards the formation of an unprecedented N-oxide.
Funder
Natural Sciences and Engineering Research Council of Canada
Fonds de Recherche du Québec Nature et Technologies
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00490C
Reference58 articles.
1. Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
2. Selective Catalytic Oxidation of CH Bonds with Molecular Oxygen
3. Towards mild metal-catalyzed C–H bond activation
4. Biologically inspired oxidation catalysis
5. Metal-centered oxygen atom transfer reactions
Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Homogeneous oxidative transformations mediated by copper catalyst systems;Coordination Chemistry Reviews;2021-08
2. Reactivity of bio-inspired Cu(II) (N2/Py2) complexes with peroxide at room temperature;Journal of Inorganic Biochemistry;2019-08
3. Biomimetic Cu/Nitroxyl Catalyst Systems for Selective Alcohol Oxidation;Catalysts;2019-04-26
4. Benzothiazole integrated into a cryptand for ESIPT-based selective chemosensor for Zn2+ ions;Dalton Transactions;2019
5. Click. Coordinate. Catalyze. Using CuAAC Click Ligands in Small‐Molecule Model Chemistry of Tyrosinase;ChemCatChem;2018-11-20
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3