Radiolysis of supercritical water at 400 °C: density dependence of the rate constant for the reaction of hydronium ions with hydrated electrons-Reference-Cited by-同舟云学术

Radiolysis of supercritical water at 400 °C: density dependence of the rate constant for the reaction of hydronium ions with hydrated electrons

Published:2019 Issue:18 Volume:21 Page:9141-9144
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Meesungnoen Jintana¹²³⁴⁵^ORCID,Jay-Gerin Jean-Paul¹²³⁴⁵^ORCID

Affiliation:

1. Département de Médecine Nucléaire et de Radiobiologie

2. Faculté de Médecine et des Sciences de la Santé

3. Université de Sherbrooke

4. Sherbrooke

5. Canada

Abstract

The rate constant, k(e_aq⁻ + H₃O⁺), for the reaction of hydronium ions with hydrated electrons in supercritical water at 400 °C has been evaluated as a function of water density over the range of 0.15–0.6 g cm⁻³.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP01190K

Reference37 articles.

1. D. Guzonas , R.Novotny , S.Penttilä , A.Toivonen and W.Zheng , Materials and Water Chemistry for Supercritical Water-cooled Reactors , Woodhead Publishing (Elsevier) , Duxford, U.K. , 2018

2. U.S. Department of Energy (U.S. DOE) , A Technology Roadmap for Generation IV Nuclear Energy Systems, Report GIF-002-00 , U.S. DOE Nuclear Energy Research Advisory Committee and the Generation IV International Forum , Washington, DC , 2002

3. Handbook of Generation IV Nuclear Reactors , ed. I. L. Pioro , Woodhead Publishing (Elsevier) , Duxford, U.K. , 2016

4. Conceptual design study of advanced power reactors

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Stress Corrosion Cracking in Austenitic Stainless Steels in Reactor Primary Water–High Purity Oxidizing and in Supercritical Conditions;Materials Performance and Characterization;2021-03-23

2. Interaction of hydrogen with actinide dioxide (011) surfaces;The Journal of Chemical Physics;2020-07-07

3. Formation of Local, Transient “Acid Spikes” in the Fast Neutron Radiolysis of Supercritical Water at 400 °C: A Potential Source of Corrosion in Supercritical Water-Cooled Reactors?;Journal of Nuclear Engineering and Radiation Science;2020-06-05

4. Yields of primary species in the low-linear energy transfer radiolysis of water in the temperature range of 25–700 °C;Physical Chemistry Chemical Physics;2020