Ferro- and antiferromagnetic coupling in a chlorido-bridged, tetranuclear Cu(ii) complex

Author:

Grosshauser Michael123,Comba Peter123,Kim Jee Young4567,Ohto Keisuke4567,Thuéry Pierre89101112,Lee Young Hoon131415,Kim Yang131415,Harrowfield Jack161718

Affiliation:

1. Universität Heidelberg

2. Anorganisch-Chemisches Institut

3. D-69120 Heidelberg, Germany

4. Department of Chemistry & Applied Chemistry

5. Faculty of Science & Engineering

6. Saga University

7. Saga 840-8502, Japan

8. CEA

9. IRAMIS

10. UMR 3299 CEA/CNRS

11. SIS2M

12. LCCEf

13. Department of Chemistry & Advanced Materials

14. Kosin University

15. Busan 606-701, South Korea

16. ISIS

17. Université de Strasbourg

18. 67083 Strasbourg, France

Abstract

A binuclear complex of copper(ii) chloride with a heptadentate bispidine-like ligand undergoes dimerisation in the solid state involving chloride bridging and leading to both ferro- and antiferromagnetic coupling of the Cu(ii) centres.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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