Nickel L-edge and K-edge X-ray absorption spectroscopy of non-innocent Ni[S2C2(CF3)2]2n series (n = −2, −1, 0): direct probe of nickel fractional oxidation state changes-Reference-Cited by-同舟云学术

Nickel L-edge and K-edge X-ray absorption spectroscopy of non-innocent Ni[S2C2(CF3)2]2n series (n = −2, −1, 0): direct probe of nickel fractional oxidation state changes

Published:2014 Issue:17 Volume:43 Page:6406-6413
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Gu Weiwei¹²³,Wang Hongxin¹²³⁴⁵,Wang Kun⁶⁷⁸

Affiliation:

1. Physical Biosciences Division

2. Lawrence Berkeley National Laboratory

3. Berkeley, USA

4. Department of Chemistry

5. University of California

6. Corporate Strategic Research

7. ExxonMobil Research and Engineering Co.

8. Annandale, USA

Abstract

Ni L- and K-edge X-ray absorption spectroscopies reveal Ni oxidation state changes experimentally and quantitatively ∼30% with 1-electron oxidation for Ni[S₂C₂(CF₃)₂]₂ⁿ.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00308J

Reference58 articles.

1. Density Functional Derived Structures and Molecular Properties of Nickel Dithiolenes and Related Complexes

2. Coordination compounds with delocalized ground states. Transition metal derivatives of dithiodiketones and ethylene-1,2-dithiolates (metal dithienes)

3. Description of the Ground State Wave Functions of Ni Dithiolenes Using Sulfur K-edge X-ray Absorption Spectroscopy

4. Sulfur K-Edge X-ray Absorption Spectroscopy as a Probe of Ligand−Metal Bond Covalency: Metal vs Ligand Oxidation in Copper and Nickel Dithiolene Complexes

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