Stereoselective ozonolysis of TMS-substituted allylic alcohol derivatives and synthesis of 14R,15S- and 14S,15S-diHETE-Reference-Cited by-同舟云学术

Stereoselective ozonolysis of TMS-substituted allylic alcohol derivatives and synthesis of 14R,15S- and 14S,15S-diHETE

Published:2018 Issue:41 Volume:16 Page:7636-7647
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Saito Shun¹²³⁴,Yamazaki Takashi⁵⁶⁷⁸⁴^ORCID,Kobayashi Yuichi¹²³⁴^ORCID

Affiliation:

1. Department of Biotechnology

2. Tokyo Institute of Technology

3. Yokohama 226-8501

4. Japan

5. Division of Applied Chemistry

6. Institute of Engineering

7. Tokyo University of Agriculture and Technology

8. Koganei 184-8588

Abstract

Ozonolysis of (E)- and (Z)-TMS-allylic alcohol derivatives gave anti and syn isomers of dihydroxyl aldehyde derivatives. This ozonolysis was applied for the synthesis of 14,15-diHETE.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB02116C

Reference33 articles.

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