β-Diketiminate calcium hydride complexes: the importance of solvent effects-Reference-Cited by-同舟云学术

β-Diketiminate calcium hydride complexes: the importance of solvent effects

Published:2017 Issue:6 Volume:46 Page:1822-1831
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Causero Andrea¹²³⁴,Ballmann Gerd¹²³⁴,Pahl Jürgen¹²³⁴,Färber Christian¹²³⁴,Intemann Julia¹²³⁴,Harder Sjoerd¹²³⁴^ORCID

Affiliation:

1. Inorganic and Organometallic Chemistry

2. Friedrich-Alexander-Universität Erlangen-Nürnberg

3. 91058 Erlangen

4. Germany

Abstract

β-Diketiminate calcium hydride complexes of the type [(DIPPnacnac)CaH·S]₂(S = Et₂O,N-Me-morpholine, DABCO) have been obtained. The solvent molecule plays a crucial part in stabilization towards ligand exchange and precipitation of CaH₂.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04659B

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