β-Diketiminate calcium hydride complexes: the importance of solvent effects
Author:
Affiliation:
1. Inorganic and Organometallic Chemistry
2. Friedrich-Alexander-Universität Erlangen-Nürnberg
3. 91058 Erlangen
4. Germany
Abstract
β-Diketiminate calcium hydride complexes of the type [(DIPPnacnac)CaH·S]2(S = Et2O,N-Me-morpholine, DABCO) have been obtained. The solvent molecule plays a crucial part in stabilization towards ligand exchange and precipitation of CaH2.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04659B
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