Rongalite/iodine-mediated C(sp<sup>3</sup>)–H bond oximation and thiomethylation reaction of methyl ketones using copper nitrate as the [NO] reagent: synthesis of thiohydroximic acids-Reference-Cited by-同舟云学术

Rongalite/iodine-mediated C(sp³)–H bond oximation and thiomethylation reaction of methyl ketones using copper nitrate as the [NO] reagent: synthesis of thiohydroximic acids

Published:2024 Issue: Volume: Page:
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wang Miao¹^ORCID,Ren Hui-Ying¹²,Pu Xiao-Yu¹,Zhang Xiao-Lu¹,Zhu He-Ying¹,Wu An-Xin³^ORCID,Zhao Bang-Tun¹

Affiliation:

1. College of Chemistry and Chemical Engineering, Key Laboratory of Function-Oriented Porous Materials of Henan Province, Luoyang Normal University, Luoyang, Henan 471934, P. R. China

2. College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China

3. National Key Laboratory of Green Pesticide, International Joint Research Center for Intelligent Biosensor Technology and Health, Central China Normal University, Wuhan 430079, P.R. China

Abstract

Rongalite/iodine-mediated oxime formation reaction for the synthesis of thiohydroximic acids from methyl ketones by employing copper nitrate as the [NO] reagent was developed.

Funder

Higher Education Discipline Innovation Project

Natural Science Foundation of Henan Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB01217H

Reference60 articles.

1. Copper nitrate: a privileged reagent for organic synthesis

2. Metal Nitrate Mediated Regioselective Nitration of BN-Substituted Arenes

3. Using weak interactions to control C–H mono-nitration of indolines

4. Meta-Selective CAr–H Nitration of Arenes through a Ru3(CO)12-Catalyzed Ortho-Metalation Strategy

5. Copper Nitrate Mediated Regio- and Stereoselective Difunctionalization of Alkynes: A Direct Approach to α-Chloro-β-nitroolefins