Formation of phosphine imide (HNPH3) and its phosphinous amide (H2N–PH2) isomer

Author:

Zhu Cheng12345ORCID,Bergantini Alexandre12345ORCID,Singh Santosh K.12345,Kaiser Ralf I.12345ORCID,Eckhardt André K.678910ORCID,Schreiner Peter R.678910ORCID,Huang Ya-Syuan1111213,Sun Bing-Jian1111213,Chang Agnes H. H.1111213

Affiliation:

1. Department of Chemistry

2. University of Hawaii at Manoa

3. 2545 McCarthy Mall

4. Honolulu

5. USA

6. Institute of Organic Chemistry

7. Justus Liebig University

8. Heinrich-Buff-Ring 17

9. Giessen 35392

10. Germany

11. National Dong Hwa University

12. Shoufeng

13. Taiwan

Abstract

Phosphine imide (HNPH3)–the simplest iminophosphorane–and phosphinous amide (H2N–PH2) were prepared by exposing phosphine–ammonia ices to ionizing radiation.

Funder

National Aeronautics and Space Administration

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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