Visible light triggered photo-decomposition of vinyl azides to (E)-stilbene derivatives via 1,2-acyl migration
Author:
Affiliation:
1. Applied Organic Chemistry Group
2. Chemical Sciences & Technology Division
3. CSIR-North East Institute of Science & Technology (NEIST)
4. Jorhat-785006
5. India
6. Department of Chemistry
7. Indian Institute of Technology
8. Guwahati-781039
Abstract
Photo-decomposition of vinyl azides into corresponding (E)-stilbenes via neighboring amino group assisted ring opening of 2H-azirines, 1,2-acyl migration and enolization.
Funder
Council of Scientific and Industrial Research, India
Department of Science and Technology, Ministry of Science and Technology
University Grants Commission
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01035A
Reference57 articles.
1. Organic Azides: An Exploding Diversity of a Unique Class of Compounds
2. Recent advances in transition metal-catalyzed N-atom transfer reactions of azides
3. α-Substituted vinyl azides: an emerging functionalized alkene
4. Vinyl Azides as Versatile Synthons for the Synthesis of Nitrogen-containing Heterocycles
5. Cu-Catalyzed Azide−Alkyne Cycloaddition
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