Unusual kinetics of poly(ethylene glycol) oxidation with cerium(iv) ions in sulfuric acid medium and implications for copolymer synthesis-Reference-Cited by-同舟云学术

Unusual kinetics of poly(ethylene glycol) oxidation with cerium(iv) ions in sulfuric acid medium and implications for copolymer synthesis

Published:2015 Issue:10 Volume:17 Page:6713-6717
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Szymański Jan K.¹²³⁴,Temprano-Coleto Fernando⁵⁶⁷⁸,Pérez-Mercader Juan¹²³⁴⁹

Affiliation:

1. Department of Earth and Planetary Sciences

2. Harvard University

3. Cambridge

4. USA

5. Escuela Técnica Superior de Ingenieros Industriales

6. Universidad Politécnica de Madrid

7. Madrid

8. Spain

9. Santa Fe Institute

Abstract

Complex aqueous phase equilibria influence the kinetics of polyalcohol–cerium(iv) reaction in sulfuric acid medium. Zeroth-order kinetics, not previously reported in such systems, results for certain sulfate ion concentrations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05693K

Reference26 articles.

1. G. Odian , Principles of Polymerization, Wiley-Interscience, 4th edn, 2004

2. Redox polymerization

3. Aqueous polymerization of methyl methacrylate initiated by Ce(IV)-alcohol redox systems: Effect of acid concentration and additives

4. Redox polymerization

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