Site-selective methylene C–H oxidation of an alkyl diamine enabled by supramolecular recognition using a bioinspired manganese catalyst-Reference-Cited by-同舟云学术

Site-selective methylene C–H oxidation of an alkyl diamine enabled by supramolecular recognition using a bioinspired manganese catalyst

Published:2023 Issue: Volume:244 Page:51-61
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Vicens Arnau¹,Vicens Laia¹^ORCID,Olivo Giorgio²^ORCID,Lanzalunga Osvaldo²^ORCID,Di Stefano Stefano²^ORCID,Costas Miquel¹^ORCID

Affiliation:

1. Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Campus de Montilivi, 17071 Girona, Spain

2. Dipartimento di Chimica and Istituto CNR di Metodologie Chimiche (IMC-CNR), Sezione Meccanismi di Reazione, Sapienza Università di Roma, P.le A. Moro 5, I-00185 Rome, Italy

Abstract

A manganese catalyst equipped with 18-benzo-6-crown ether receptors has been employed in the catalytic oxidation of tetradecane-1,14-diamine. Binding of the protonated amines results in selective (up to 92%) oxidation of the C6/C7 methylenic sites.

Funder

Institució Catalana de Recerca i Estudis Avançats

Ministerio de Ciencia e Innovación

Elsevier Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/FD/D2FD00177B

Reference41 articles.

1. If CH Bonds Could Talk: Selective CH Bond Oxidation