Stoichiometry-controlled structural and functional variation in two photochromic iodoargentates with a fast and wide range response

Abstract

Two MCMP⁺/iodoargentate hybrids have been synthesized and they exhibit rare electron transfer photochromsim with a fast response rate, a wide response range and a long-lived charge-separated state, which is largely ascribed to the flexible aggregation of electron-deficient MCMP⁺ counterions.