Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions-Reference-Cited by-同舟云学术

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Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions

Published:2018 Issue:8 Volume:9 Page:2195-2211
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Iwasaki Takanori¹²³⁴⁵^ORCID,Fukuoka Asuka¹²³⁴⁵,Yokoyama Wataru¹²³⁴⁵,Min Xin¹²³⁴⁵,Hisaki Ichiro⁶²³⁴⁵^ORCID,Yang Tao⁷⁸⁹⁵¹⁰^ORCID,Ehara Masahiro⁷⁸⁹⁵¹⁰^ORCID,Kuniyasu Hitoshi¹²³⁴⁵,Kambe Nobuaki¹²³⁴⁵

Affiliation:

1. Department of Applied Chemistry

2. Graduate School of Engineering

3. Osaka University

4. Osaka 565-0871

5. Japan

6. Department of Material and Life Science

7. Department of Theoretical and Computational Molecular Science

8. Institute for Molecular Science

9. Okazaki

10. Elements Strategy Initiative for Catalysts and Batteries (ESICB)

Abstract

The detailed reaction mechanism of anionic Ni complex-promoted C–C bond forming reactions was clarified by experimental and theoretical methods.

Funder

Japan Society for the Promotion of Science

Institute for Molecular Science

Ube Foundation

Uehara Memorial Foundation

Sumitomo Foundation

Iketani Science and Technology Foundation

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04675H

Reference104 articles.

1. Multicomponent one-pot annulations forming 3 to 6 bonds

2. Multiple-Component Condensation Strategies for Combinatorial Library Synthesis

3. Maximizing Synthetic Efficiency: Multi-Component Transformations Lead the Way

4. .pi.-Allylmetal derivatives in organic synthesis

5. Nickel: An Element with Wide Application in Industrial Homogeneous Catalysis

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2. Lanthanum-Catalyzed Stereospecific Cross-Coupling of Propargylic Substrates with Grignard Reagents;Organic Letters;2023-09-06

3. Synthesis of Fluorinated Compounds by Nickel-Catalyzed Defluorinative Cross-Coupling Reactions;ACS Catalysis;2023-09-01

4. Transition‐Metal‐Catalyzed Alkyl–Alkyl Cross‐Coupling Reactions;Organic Reactions;2023-08-09

5. Nickel-Catalyzed Reductive Three-Component Cross-Coupling of Butadiene with Aldehydes and Alkenyl Triflates/Bromides: Access to Skipped Dienes;Organic Letters;2023-04-26

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