Selective Pd recovery from acidic leachates by 3-mercaptopropylphosphonic acid grafted TiO2: does surface coverage correlate to performance?

Author:

Gys Nick12ORCID,Pawlak Bram3ORCID,Lufungula Léon Luntadila4ORCID,Marcoen Kristof5ORCID,Wyns Kenny1,Baert Kitty5,Atia Thomas Abo16,Spooren Jeroen1ORCID,Adriaensens Peter3ORCID,Blockhuys Frank4ORCID,Hauffman Tom5,Meynen Vera12ORCID,Mullens Steven1,Michielsen Bart1ORCID

Affiliation:

1. Sustainable Materials, Flemish Institute for Technological Research (VITO NV), Boeretang 200, Mol 2400, Belgium

2. Laboratory of Adsorption and Catalysis (LADCA), Department of Chemistry, University of Antwerp, Universiteitsplein 1, Wilrijk 2610, Belgium

3. Analytical and Circular Chemistry (ACC), Institute for Materials Research (IMO), Hasselt University, Agoralaan 1, Diepenbeek 3590, Belgium

4. Structural Chemistry Group, Department of Chemistry, University of Antwerp, Groenenborgerlaan 171, Antwerp 2020, Belgium

5. Research Group Electrochemical and Surface Engineering (SURF), Department Materials and Chemistry, Vrije Universiteit Brussel, Pleinlaan 2, Brussels 1050, Belgium

6. Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven 3000, Belgium

Abstract

Concentration-controlled surface coverages of 3-mercaptopropylphosphonic acid grafted TiO2 allows tailoring the selectivity towards Pd during sorption in a complex acidic leachate originating from a spent automotive exhaust catalyst.

Funder

H2020 Societal Challenges

Fonds Wetenschappelijk Onderzoek

Universiteit Hasselt

Vlaamse regering

Universiteit Antwerpen

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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