Synthesis, C–H bond functionalisation and cycloadditions of 6-styryl-1,2-oxathiine 2,2-dioxides

Author:

Gabbutt Christopher D.12345ORCID,Heron B. Mark12345ORCID,Lilly Thomas12345,Ogwang Ochola W.12345,Zonidis Dimitrios12345ORCID

Affiliation:

1. Department of Chemical Sciences

2. School of Applied Sciences

3. University of Huddersfield

4. Huddersfield

5. UK

Abstract

1,2-Oxathiine 2,2-dioxides readily undergo C–H activated coupling at C-3. The 6-styryl derivatives participate in cycloadditions with PTAD to afford 1H-[1,2]oxathiino[5,6-c][1,2,4]triazolo[1,2-a]pyridazine-1,3(2H)-dione 8,8-dioxides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference51 articles.

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3. M. J. Cook , Chapter 2.26: Six-membered Rings with More than One Oxygen or Sulfur Atom , in Comprehensive Heterocyclic Chemistry , ed. A. J. Boulton and A. McKillop , 1984 , vol. 3 , pp. 943–994

4. E. Kleinpeter , Chapter 8.10: 1,2-Dioxins, Oxathiins, Dithiins, and their Benzo Derivatives , in Comprehensive Heterocyclic Chemistry III , ed. A. Aitken , 2008 , vol. 8 , pp. 677–738

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1. Six-membered ring systems: with O and/or S atoms;Progress in Heterocyclic Chemistry;2023

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