Doyle–Kirmse reaction using 3,3-difluoroallyl sulfide and N-sulfonyl-1,2,3-triazole: an efficient access to gem-difluoroallylated multifunctional quaternary carbon-Reference-Cited by-同舟云学术

Doyle–Kirmse reaction using 3,3-difluoroallyl sulfide and N-sulfonyl-1,2,3-triazole: an efficient access to gem-difluoroallylated multifunctional quaternary carbon

Published:2021 Issue:32 Volume:19 Page:6974-6978
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wang Jiazhuang¹,Yu Jingwen¹,Chen Junyu¹,Jiang Yubo¹,Xiao Tiebo¹^ORCID

Affiliation:

1. Faculty of Science, Kunming University of Science and Technology, Jingming South Road 727, Chenggong District, Kunming 650500, P. R. of China

Abstract

A Rh(ii)-catalyzed Doyle–Kirmse reaction of N-sulfonyl-1,2,3-triazole with 3,3-difluoroallyl sulfide been developed, which provides an efficient access to gem-difluoroallyl containing multifunctional quaternary center.

Funder

National Natural Science Foundation of China

Major Science and Technology Projects in Yunnan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01129D

Reference71 articles.

1. Stereoselective Construction of Quaternary Carbon Stereocenters via a Semipinacol Rearrangement Strategy

2. Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters