A new family of anti-perovskite oxyhydrides with tetrahedral GaO4 polyanions

Author:

Ayu Nur Ika Puji12,Takeiri Fumitaka2345ORCID,Ogawa Takafumi6ORCID,Kuwabara Akihide6ORCID,Hagihala Masato12ORCID,Saito Takashi12ORCID,Kamiyama Takashi1278ORCID,Kobayashi Genki235ORCID

Affiliation:

1. Neutron Science Laboratory (KENS), Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), 203-1 Shirakata, Tokai, Ibaraki 319-1106, Japan

2. SOKENDAI (The Graduate University for Advanced Studies), Shonan Village, Hayama, Kanagawa 240-0193, Japan

3. Department of Materials Molecular Science, Institute for Molecular Science, 38 Nishigonaka, Myodaiji, Okazaki, Aichi 444-8585, Japan

4. PRESTO, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012, Japan

5. Solid State Chemistry Laboratory, Cluster for Pioneering Research (CPR), RIKEN, Wako 351-0198, Japan

6. Nanostructures Research Laboratory, Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta-ku, Nagoya 456-8587, Japan

7. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China

8. China Spallation Neutron Source Science Center, Dongguan, 523803, China

Abstract

Solid compounds A3−xGaO4H1−y (A = Sr, Ba; x ∼0.15, and y ∼0.3) have been successfully synthesized. This is a new family of anti-perovskite type compounds with p-metalcentered tetrahedral polyanions.

Funder

Japan Science and Technology Agency

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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