N-Heterocyclic carbene adducts to [Cp′FeI]2: synthesis and molecular and electronic structure
Author:
Affiliation:
1. Institut für Anorganische und Analytische Chemie
2. Technische Universität Braunschweig
3. 38106 Braunschweig
4. Germany
Abstract
Adducts [Cp′FeI(NHC)] exhibit a highly anisotropic magnetic Ms = ±2 ground state resulting in unusual large spin–lattice (Orbach) relaxation barriers observed by zero-field 57Fe Mössbauer spectroscopy.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/QI/C5QI00235D
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