Rh-catalyzed decarbonylation of conjugated ynones via carbon–alkyne bond activation: reaction scope and mechanistic exploration via DFT calculations-Reference-Cited by-同舟云学术

Rh-catalyzed decarbonylation of conjugated ynones via carbon–alkyne bond activation: reaction scope and mechanistic exploration via DFT calculations

Author:

Dermenci Alpay¹²³⁴,Whittaker Rachel E.¹²³⁴,Gao Yang⁵⁶⁷⁸⁹,Cruz Faben A.¹²³⁴,Yu Zhi-Xiang⁵⁶⁷⁸⁹,Dong Guangbin¹²³⁴

Affiliation:

1. The University of Texas at Austin

2. Department of Chemistry

3. Austin

4. USA

5. Beijing National Laboratory of Molecular Sciences (BNLMS)

6. Key Laboratory of Bioorganic Chemistry and Molecular Engineering

7. College of Chemistry

8. Peking University

9. Beijing

Abstract

We report a catalytic C–C bond activation of unstrained conjugated monoynonesviadecarbonylation to synthesize disubstituted alkynes.

Funder

National Institute of General Medical Sciences

Cancer Prevention and Research Institute of Texas

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

Reference71 articles.

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