Phase separation of binary mixtures induced by soft centrifugal fields

Author:

Zemb Thomas123ORCID,Rosenberg Rose456,Marčelja Stjepan789,Haffke Dirk456,Dufrêche Jean-François123ORCID,Kunz Werner10116ORCID,Horinek Dominik10116ORCID,Cölfen Helmut456ORCID

Affiliation:

1. Institute for Separation Chemistry ICSM U Montpellier/CEA/CNRS/ENSCM

2. Marcoule

3. France

4. Physical Chemistry, Department of Chemistry, University of Konstanz

5. D-78457 Konstanz

6. Germany

7. Applied Maths, RSPhys, ANU, ACT 2601

8. Canberra

9. Australia

10. Institute of Physical and Theoretical Chemistry, University of Regensburg

11. D-93040 Regensburg

Abstract

We use the model system ethanol–dodecane to demonstrate that giant critical fluctuations induced by easily accessible weak centrifugal fields as low as 2000g can be observed above the miscibility gap even far from the critical point of a binary liquid mixture.

Funder

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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