A quinoxaline-fused tetrathiafulvalene derivative and its semiconducting charge-transfer salt: synthesis, crystal structures and physical properties

Author:

Geng Yan123,Fiolka Christoph123,Krämer Karl123,Hauser Jürg123,Laukhin Vladimir45678,Decurtins Silvio123,Liu Shi-Xia123

Affiliation:

1. Departement für Chemie und Biochemie

2. Universität Bern

3. CH-3012 Bern, Switzerland

4. Institució Catalana de Recerca i Estudis Avançats (ICREA)

5. 08010 Barcelona, Spain

6. Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)

7. Campus de la UAB

8. Bellaterra 08193, Spain

Abstract

A quinoxaline-fused tetrathiafulvalene (TTF) derivative 1 has been synthesized to form a compact and planar π-conjugated donor–acceptor (D–π–A) ensemble, and its single crystal structure has been determined by X-ray diffraction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference39 articles.

1. J. Yamada and T.Sugimoto , TTF Chemistry. Fundamentals and applications of Tetrathiafulvalene , Springer Verlag , Berlin , 2004

2. J. M. Williams , J. R.Ferraro , R. J.Thorn , K. D.Carlson , U.Geiser , H. H.Wang , A. M.Kini and M.-H.Whangbo , Organic Superconductors (including Fullerenes) , Prentice Hall , Englewod Cliffs , 1992

3. Magnetic TTF-Based Charge-Transfer Complexes

4. New Concepts in Tetrathiafulvalene Chemistry

5. Tetrathiafulvalene (TTF) derivatives: key building-blocks for switchable processes

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