Eight coordinated mononuclear dysprosium complexes of heptadentate aminophenol ligands: the influence of the phenol substituents and the ancillary donors on the magnetic relaxation-Reference-Cited by-同舟云学术

Eight coordinated mononuclear dysprosium complexes of heptadentate aminophenol ligands: the influence of the phenol substituents and the ancillary donors on the magnetic relaxation

Published:2021 Issue:43 Volume:50 Page:15878-15887
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fondo Matilde¹^ORCID,Corredoira-Vázquez Julio¹^ORCID,García-Deibe Ana M.¹^ORCID,Sanmartín-Matalobos Jesús¹^ORCID,Reta Daniel²^ORCID,Colacio Enrique³^ORCID

Affiliation:

1. Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain

2. Departament de Química Inorgànica i Orgànica, Facultat de Química, Universitat de Barcelona, 08028 Barcelona, Spain

3. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain

Abstract

Distorted square antiprism DyIII SIMs of heptadentate aminophenol ligands decrease their Ueff with the electron-withdrawing ability of the phenol substituents and the increasing electronegativity of auxiliary monodentate donors.

Funder

Ministerio de Ciencia, Innovación y Universidades

Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02756E

Reference43 articles.

1. Exploiting single-ion anisotropy in the design of f-element single-molecule magnets

2. Improving f-element single molecule magnets

3. Large magnetic anisotropy in mononuclear metal complexes

4. Enriching lanthanide single-ion magnetism through symmetry and axiality

5. Molecular magnetism of lanthanide: Advances and perspectives

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