Mechanism of nickel-catalyzed direct carbonyl-Heck coupling reaction: the crucial role of second-sphere interactions-Reference-Cited by-同舟云学术

Mechanism of nickel-catalyzed direct carbonyl-Heck coupling reaction: the crucial role of second-sphere interactions

Published:2021 Issue:7 Volume:50 Page:2654-2662
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bian Jian-Hong¹²³⁴,Tong Wen-Yan¹²³⁴,Pitsch Chloe E.⁵⁶⁷⁸,Wu Yan-Bo¹²³⁴^ORCID,Wang Xiaotai⁹¹⁰¹¹⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province and Institute of Molecular Science

2. Shanxi University

3. Taiyuan 030006

4. P. R. China

5. Department of Chemistry

6. University of Colorado Denver

7. Denver

8. USA

9. Hoffmann Institute of Advanced Materials

10. Shenzhen Polytechnic

11. Shenzhen 518055

Abstract

We present a detailed DFT mechanistic study on the first Ni-catalyzed direct carbonyl-Heck coupling of aryl triflates and aldehydes to afford ketones.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanxi Province

Shanxi University

University of Colorado Denver

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04121A

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