Predicting the α-relaxation time of glycerol confined in 1.16 nm pores of zeolitic imidazolate frameworks

Author:

Ngai K. L.1234ORCID,Lunkenheimer P.56789ORCID,Loidl A.56789ORCID

Affiliation:

1. CNR-IPCF

2. Largo Bruno Pontecorvo 3

3. I-56127 Pisa

4. Italy

5. Experimental Physics V

6. Center for Electronic Correlations and Magnetism

7. University of Augsburg

8. Augsburg

9. Germany

Abstract

Relaxation times of glycerol confined in 1.16 nm ZIF pores found by Uhl et al. [J. Chem. Phys., 2019, 150, 024504] are explained quantitatively by the Coupling Model.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference40 articles.

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4. M. Wübbenhorst and S.Napolitano , Deviations from bulk glass transition dynamics of small molecule glass formers: some scenarios in relation to the dimensionality of the confining geometry , in Dynamics in Geometrical Confinement , ed. F. Kremer , Springer , 2014 , pp. 247–277

5. Glassy dynamics of polymers confined to nanoporous glasses revealed by relaxational and scattering experiments

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