Covalency hinders AnO2(H2O)+ → AnO(OH)2+ isomerisation (An = Pa

Covalency hinders AnO2(H2O)+ → AnO(OH)2+ isomerisation (An = Pa–Pu)

Published:2016 Issue:7 Volume:45 Page:3158-3162
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kaltsoyannis Nikolas¹²³⁴

Affiliation:

1. School of Chemistry

2. The University of Manchester

3. Manchester M13 9PL

4. UK

Abstract

Computational analysis of the electronic structures of AnO₂(H₂O)⁺ (An = Pa–Pu) demonstrates that isomerisation to AnO(OH)₂⁺ is least favoured for the system with the most covalent An–O_yl bond.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04317D

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