Influence of the Lewis basicity hardness of crystallization solvents on the coordination sphere of the complex [Co(3,5-dinitrobenzoate-O,O′)<sub>2</sub>]: crystallographic and theoretical analysis-Reference-Cited by-同舟云学术

Influence of the Lewis basicity hardness of crystallization solvents on the coordination sphere of the complex [Co(3,5-dinitrobenzoate-O,O′)₂]: crystallographic and theoretical analysis

Published:2022 Issue:16 Volume:24 Page:2982-2991
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Fonseca Daniela¹,Pérez-Torres Andrés F.²,Cobo Justo³,Zapata-Rivera Jhon⁴^ORCID,Hurtado John J.¹^ORCID,Macías Mario A.²^ORCID

Affiliation:

1. Inorganic Chemistry, Catalysis and Bio-inorganic Group, Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-12, 111711 Bogotá, Colombia

2. Crystallography and Chemistry of Materials, CrisQuimMat, Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-10, 111711 Bogotá, Colombia

3. Departamento de Química Inorgánica y Orgánica Campus las Lagunillas, Universidad de Jaén, E-23071 Jaén, Spain

4. Molecular Electronic Structure Group, Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-10, 111711 Bogotá, Colombia

Abstract

Crystal growth of [Co(DNB)2] in different solvents is a thermodynamic process favored by ΔErecrys (kcal mol−1) where mono/trinuclear molecules are obtained. Closeness of HOMO orbitals of solvents to the SOMOs orbitals of Co(ii) ions guide the process.

Funder

Universidad de Jaén

Universidad de los Andes

Junta de Andalucía

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CE/D2CE00177B

Reference48 articles.

1. Structural Diversity, Thermal Studies, and Luminescent Properties of Metal Complexes of Dinitrobenzoates: A Single Crystal to Single Crystal Transformation from Dimeric to Polymeric Complex of Copper(II)