Evidencing an elusive conical intersection in the dissociative photoionization of methyl iodide-Reference-Cited by-同舟云学术

Evidencing an elusive conical intersection in the dissociative photoionization of methyl iodide

Published:2024 Issue:9 Volume:15 Page:3203-3213
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

González-Vázquez Jesús¹²^ORCID,García Gustavo A.³^ORCID,Chicharro David V.⁴^ORCID,Bañares Luis⁴⁵^ORCID,Poullain Sonia Marggi⁴^ORCID

Affiliation:

1. Departamento de Química, Facultad de Ciencias, Universidad Autónoma de Madrid, Spain

2. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain

3. Synchrotron SOLEIL, L'Orme des Merisiers, St. Aubin, BP 48, 91192 Gif-sur-Yvette, France

4. Departamento de Química Física, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain

5. Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-Nanoscience), Cantoblanco, 28049 Madrid, Spain

Abstract

The valence-shell dissociative ionization of methyl iodide is studied using electron ion coincidence spectroscopy in combination with synchrotron radiation, revealing a conical intersection between the ground and first excited states of the cation.

Funder

Comunidad de Madrid

Ministerio de Ciencia e Innovación

Universidad Complutense de Madrid

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC04065H

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