The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; nitrite reduction mediated by a V(iii) complex
Author:
Affiliation:
1. Department of Chemistry
2. National Cheng Kung University
3. Tainan 701
4. Taiwan
5. National Taiwan University
6. Taipei 106
Abstract
A V(iii) complex demonstrates the reactivity of nitrite reduction without adding external protons or oxophilic substrates. In this reaction, the V(iii) ion plays dual functions: the site for substrate binding and oxygen-atom-transfer reagent.
Funder
Ministry of Science and Technology, Taiwan
National Cheng Kung University
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03274C
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1. Mechanistic studies of nitrite reactions with metalloproteins and models relevant to mammalian physiology
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4. A brief history of hemoglobins: plant, animal, protist, and bacteria.
5. The functional nitrite reductase activity of the heme-globins
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