U- to Z-shape isomerization in a Pt2Ag2 framework containing pyridyl-NHC ligands-Reference-Cited by-同舟云学术

U- to Z-shape isomerization in a Pt2Ag2 framework containing pyridyl-NHC ligands

Published:2018 Issue:21 Volume:47 Page:7113-7117
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Horiuchi Shinnosuke¹²³⁴⁵^ORCID,Moon Sangjoon¹²³⁴⁵,Sakuda Eri¹²³⁴⁵^ORCID,Ito Akitaka⁶⁷⁸⁵^ORCID,Arikawa Yasuhiro¹²³⁴⁵^ORCID,Umakoshi Keisuke¹²³⁴⁵^ORCID

Affiliation:

1. Division of Chemistry and Materials Science

2. Graduate School of Engineering

3. Nagasaki University

4. Nagasaki 852-8521

5. Japan

6. Graduate School of Engineering/School of Environmental Science and Engineering

7. Kochi University of Technology

8. Kami

Abstract

A highly twisted U-shaped Pt₂Ag₂ complex bearing pyridyl–NHC ligands showed isomerization to Z-shaped conformations via an intermolecular process. ¹H NMR experiments revealed that the isomerization reached U : Z = 2 : 1 ratio in a thermodynamic equilibrium state.

Funder

Japan Society for the Promotion of Science

Nippon Sheet Glass Foundation for Materials Science and Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01047A

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