Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th}1− anion containing thorium in the formal +2 oxidation state-Reference-Cited by-同舟云学术

Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C5H3(SiMe3)2]3Th}1− anion containing thorium in the formal +2 oxidation state

Published:2015 Issue:1 Volume:6 Page:517-521
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Langeslay Ryan R.¹²³⁴,Fieser Megan E.¹²³⁴,Ziller Joseph W.¹²³⁴,Furche Filipp¹²³⁴,Evans William J.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of California

3. Irvine

4. USA

Abstract

Structural, spectroscopic, and DFT analysis of the first molecular complexes of Th²⁺ indicate they have a 6d² electron configuration of the type expected for the transactinide ions Rf²⁺ and Db³⁺.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03033H

Reference57 articles.

1. Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State

2. Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]

3. Expanding Rare-Earth Oxidation State Chemistry to Molecular Complexes of Holmium(II) and Erbium(II)