Boosting CO2-to-CO conversion on a robust single-atom copper decorated carbon catalyst by enhancing intermediate binding strength

Author:

Chen Shixia1234,Li Yuewei1234,Bu Zhuogang1234,Yang Fangqi1234,Luo Junhui1234,An Qizheng5236,Zeng Zheling1234ORCID,Wang Jun1234ORCID,Deng Shuguang78910ORCID

Affiliation:

1. School of Resources Environmental & Chemical Engineering

2. Nanchang University

3. Nanchang

4. China

5. School of Material Science and Engineering and Institute for Advanced Study

6. P. R. China

7. School for Engineering of Matter, Transport and Energy

8. Arizona State University

9. Tempe

10. USA

Abstract

The hydrogen-bond strengthen the *COOH adsorption and lower the CO2(g)→*COOH energy barrier on Cu–N–C electrocatalyst, simultaneously yielding a high CO FE and TOF.

Funder

Natural Science Foundation of Jiangxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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