High-efficiency ammonia synthesis via electrochemical nitrate reduction over Co3O4 nanoarrays by B doping-Reference-Cited by-同舟云学术

High-efficiency ammonia synthesis via electrochemical nitrate reduction over Co₃O₄ nanoarrays by B doping

Published:2024 Issue:8 Volume:11 Page:2339-2345
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Deng Zhiqin¹²,Liu Heng¹^ORCID,Wang Huiyong³^ORCID,Ma Chaoqun⁴,Du Juan²^ORCID,Zheng Baozhan²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, Hunan, China

2. College of Chemistry, Sichuan University, Chengdu 610064, Sichuan, China

3. College of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, Henan, China

4. School of Materials Science and Engineering, University of Science and Technology, Beijing, Beijing 100083, China

Abstract

B acts as an effective dopant to boost the catalytic activity of Co3O4 for the nitrate reduction reaction towards NH3 synthesis. Such B-Co3O4/TM achieves a high faradaic efficiency of 94.7% and a large NH3 yield rate of 407.3 μmol h−1 cm−2.

Funder

Henan Normal University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D4QI00310A

Reference46 articles.

1. Ammonia for hydrogen storage: challenges and opportunities

2. Ultrathin bismuth oxyiodide nanosheets for photocatalytic ammonia generation from nitrogen and water under visible to near-infrared light

3. Flower-like open-structured polycrystalline copper with synergistic multi-crystal plane for efficient electrocatalytic reduction of nitrate to ammonia

4. How a century of ammonia synthesis changed the world

5. How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully

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