Achmatowicz rearrangement enables hydrogenolysis-free gas-phase synthesis of pentane-1,2,5-triol from furfuryl alcohol
Author:
Affiliation:
1. Institute of Organic Chemistry with Centre of Phytochemistry
2. Bulgarian Academy of Sciences
3. 1113 Sofia
4. Bulgaria
Abstract
Hydrogenolysis-free gas-phase hydrogenation of an Achmatowicz intermediate provided pentane-1,2,5-triol in 94% overall yield from furfuryl alcohol.
Funder
Bulgarian National Science Fund
Ministry of Education and Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/GC/C9GC02888A
Reference40 articles.
1. Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
2. 5-Hydroxymethylfurfural (HMF) as a building block platform: Biological properties, synthesis and synthetic applications
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4. Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels
5. When Will 5‐Hydroxymethylfurfural, the “Sleeping Giant” of Sustainable Chemistry, Awaken?
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