Folding of fluorinated oligoarylenes into non-alternant PAHs with various topological shapes

Author:

Akhmetov Vladimir12345,Förtsch Andreas67895,Feofanov Mikhail12345ORCID,Troyanov Sergey10111213,Amsharov Konstantin12345ORCID

Affiliation:

1. Friedrich-Alexander University Erlangen-Nuernberg

2. Department of Chemistry and Pharmacy

3. Organic Chemistry II

4. 91058 Erlangen

5. Germany

6. Institute of Chemistry

7. Organic Chemistry

8. Martin-Luther-University Halle-Wittenberg

9. D-06120 Halle

10. Chemistry Department

11. Moscow State University

12. Moscow

13. Russian Federation

Abstract

An unprecedented [6]helicene's cavity closure indicating the possibility of introducing seven-membered rings via alumina-mediated C–F activation is shown.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference42 articles.

1. The era of carbon allotropes

2. D. Prenzel and R. R.Tykwinski , in Encyclopedia of Polymeric Nanomaterials , Springer Berlin Heidelberg , Berlin, Heidelberg , 2014 , pp. 1–12

3. Pentagons, heptagons and negative curvature in graphite microtubule growth

4. Diamond from graphite

5. C60: Buckminsterfullerene

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