Enantioselective formal synthesis of the marine macrolide (−)-callyspongiolide-Reference-Cited by-同舟云学术

Enantioselective formal synthesis of the marine macrolide (−)-callyspongiolide

Published:2020 Issue:41 Volume:56 Page:5536-5539
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Urbina Aina¹²³⁴⁵^ORCID,Llor Núria¹²³⁴⁵^ORCID,Barbieri Maria Vittoria¹²³⁴⁵^ORCID,Bosch Joan¹²³⁴⁵^ORCID,Amat Mercedes¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Organic Chemistry

2. Faculty of Pharmacy and Food Sciences, and Institute of Biomedicine (IBUB)

3. University of Barcelona

4. Barcelona-08028

5. Spain

Abstract

An enantioselective formal synthesis of the cytotoxic macrolide (−)-callyspongiolide, in eight steps from aldehyde 4, is reported.

Funder

Ministerio de Economía y Competitividad

Ministerio de Ciencia, Innovación y Universidades

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01978J

Reference39 articles.

1. Callyspongiolide, a Cytotoxic Macrolide from the Marine Sponge Callyspongia sp.

2. Kahalalide Derivatives from the Indian Sacoglossan Mollusk Elysia grandifolia

3. Total Synthesis and Stereochemical Assignment of Callyspongiolide

4. Enantioselective Synthesis of Both Epimers at C-21 in the Proposed Structure of Cytotoxic Macrolide Callyspongiolide

5. Enantioselective total synthesis and structural assignment of callyspongiolide

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2. Origin of the selectivity in the ring-closing metathesis step of the synthesis of (−)-callyspongiolide: Formation of fourteen-versus eight-membered rings;Tetrahedron;2022-10

3. The Synthesis and Bioactivity of the Marine Macrolide Callyspongiolide;Chemistry – A European Journal;2020-12-14

4. A Ring Closing Metathesis Approach to the Formal Synthesis of (+)‐Callyspongiolide;ChemCatChem;2020-09-07