Acid-promoted bicyclization of arylacetylenes to benzobicyclo[3.2.1]octanes through cationic rearrangements-Reference-Cited by-同舟云学术

Acid-promoted bicyclization of arylacetylenes to benzobicyclo[3.2.1]octanes through cationic rearrangements

Published:2016 Issue:24 Volume:52 Page:4537-4540
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Su Xiang¹²³⁴⁵,Sun Yihua⁶⁷⁸⁴⁵,Yao Jiannian⁶⁷⁸⁴⁵,Chen Hui⁶⁷⁸⁴⁵,Chen Chao¹²³⁴⁵

Affiliation:

1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)

2. Department of Chemistry

3. Tsinghua University

4. Beijing

5. China

6. Beijing National Laboratory for Molecular Sciences (BNLMS)

7. CAS Key Laboratory of Photochemistry Institute of Chemistry

8. Chinese Academy of Sciences

Abstract

Acid-promoted site- and stereo-selective bicyclization of alkynes to benzobicyclo[3.2.1]octanes was realized with atom- and step-economy. The reaction proceeded through two C–C bonds formed on remote alkyl C–H bonds via twice long-distance cationic rearrangement.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC00452K

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5. Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way

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