Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system-Reference-Cited by-同舟云学术

Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system

Published:2023 Issue:20 Volume:13 Page:13819-13823
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Xue¹,Guo Xinyuan²,Wang Xinmei²,Li Chi²,Wang Shanjun²,Li Han²,Gao Yan’an³^ORCID,Li Yiying⁴,Wang Jinhui¹⁵,Xu Huanjun²⁵^ORCID

Affiliation:

1. Department of Medicinal Chemistry and Natural Medicine Chemistry, College of Pharmacy, Harbin Medical University, Harbin, China

2. School of Science, Qiongtai Normal University, Haikou, 571127, China

3. Key Laboratory of Ministry of Education for Advanced Materials in Tropical, Island Resources, Hainan University, Haikou, 570228, China

4. College of Basic Medicine and Life Sciences, Hainan Medical University, Haikou, China

5. Key Laboratory of Child Cognition and Behavior Development of Hainan Province, Qiongtai Normal University, Haikou, China

Abstract

A simple and metal-free catalytic system composed of NaOtBu/DMF efficiently converted 5-HMF to FDCA with an 80.85% yield. 5-HMF analogues and various types of alcohols were also transformed to corresponding acids in satisfactory to excellent yield.

Funder

National Science and Technology Major Project

National Natural Science Foundation of China

Hainan Association for Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D3RA01104F

Reference46 articles.

1. Synthesis of Biomass‐Derived Ethers for Use as Fuels and Lubricants

2. Catalytic oxidation of carbohydrates into organic acids and furan chemicals

3. Recent advances in catalytic transformation of biomass-derived 5-hydroxymethylfurfural into the innovative fuels and chemicals

4. Catalytic conversion of 5-hydroxymethylfurfural to some value-added derivatives