Platinum diimine-dithiolate complexes as a new class of photoconducting compounds for pristine photodetectors: case study on [Pt(bipy)(Naph-edt)] (bipy = 2,2′-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate)

Author:

Aragoni M. Carla1234ORCID,Arca Massimiliano1234ORCID,Binda Maddalena5674,Caltagirone Claudia1234ORCID,Lippolis Vito1234ORCID,Natali Dario56748ORCID,Podda Enrico1234,Sampietro Marco56748,Pintus Anna1234ORCID

Affiliation:

1. Università degli Studi di Cagliari

2. Dipartimento di Scienze Chimiche e Geologiche

3. 09042 Monserrato (Cagliari)

4. Italy

5. Center for Nano Science and Technology @Polimi

6. Istituto Italiano di Tecnologia

7. 20133 Milano

8. Politecnico di Milano

Abstract

A pristine photodetector based on the heteroleptic diimine-dithiolate complex [Pt(bipy)(Naph-edt)] is reported showing EQE values (50%@600 nm) much larger than those measured for any homoleptic bis(1,2-dithiolene) metal complex.

Funder

Fondazione di Sardegna

Regione Autonoma della Sardegna

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

1. E. I.Stiefel , Dithiolene chemistry: Synthesis, properties, and applications , Wiley , Hoboken , 2003

2. M.Arca , M. C.Aragoni and A.Pintus , in Handbook of Chalcogen Chemistry , ed. F. A. Devillanova and W.-W. du Mont , RSC Publishing , Cambridge , 2013 , pp. 127–179

3. Reaction of Diphenylacetylene with Nickel Sulfides

4. M. L.Kirk , R. L.McNaughton and M. E.Helton , in Progress in Inorganic Chemistry , John Wiley and Sons Inc. , 2004 , vol. 52 , pp. 111–212

5. Neutral d8 metal bis-dithiolene complexes: Synthesis, electronic properties and applications

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