Insights into alloy/oxide or hydroxide interfaces in Ni–Mo-based electrocatalysts for hydrogen evolution under alkaline conditions

Author:

Luo Min1,Yang Jietian1,Li Xingang1ORCID,Eguchi Miharu23,Yamauchi Yusuke23ORCID,Wang Zhong-Li1ORCID

Affiliation:

1. Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

2. JST-ERATO Yamauchi Materials Space-Tectonics Project, International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1Namiki, Tsukuba, Ibaraki 305-0044, Japan

3. School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, QLD 4072, Australia

Abstract

The activity of Ni–Mo catalysts for the hydrogen evolution reaction originates from the interfaces of alloy–oxide or alloy–hydroxide, in which the oxide or hydroxide promotes water dissociation and the alloy accelerates hydrogen combination.

Funder

National Natural Science Foundation of China

Japan Science and Technology Corporation

Exploratory Research for Advanced Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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