Unexpected solvent effect on the binding of positively-charged macrocycles to neutral aromatic hydrocarbons

Author:

Wang Yu-Mei12345,Yao Huan6785,Quan Mao6785,Chai Hongxin6785,Yang Liu-Pan6785ORCID,Pan Ying-Ming12345ORCID,Jiang Wei6785ORCID

Affiliation:

1. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources

2. School of Chemistry and Pharmaceutical Sciences

3. Guangxi Normal University

4. Guilin 541004

5. China

6. Shenzhen Grubbs Institute and Department of Chemistry

7. Southern University of Science and Technology

8. Shenzhen

Abstract

A pair of positively charged naphthotubes was synthesized by using imidazolium as the linkers. Surprisingly, these naphthotubes show stronger binding affinities to neutral aromatic hydrocarbons in CD3CN than in CD2Cl2.

Funder

National Natural Science Foundation of China

Shenzhen Science and Technology Innovation Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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