Anisole hydrodeoxygenation over Ni–Co bimetallic catalyst: a combination of experimental, kinetic and DFT study

Author:

Kumar Adarsh1ORCID,Jindal Meenu23,Rawat Shivam23,Sahoo Abhisek4ORCID,Verma Rahul5,Chandra Devesh26,Kumar Sagar3,Thallada Bhaskar23ORCID,Yang Bin1ORCID

Affiliation:

1. Bioproducts, Sciences, and Engineering Laboratory, Department of Biological Systems Engineering, Washington State University, Richland, WA 99354, USA

2. Academy of Scientific and Innovative Research, Kamla Nehru Nagar, Ghaziabad 201002, India

3. Material Resource Efficiency Division, CSIR-Indian Institute of Petroleum, Dehradun 248005, India

4. Department of Chemical Engineering, Indian Institute of Technology-Delhi, New Delhi, 110016, India

5. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 20816, India

6. Chemical Technology Division, CSIR-Institute of Himalayan Bioresource Technology, Palampur, HP 176 061, India

Abstract

High reducible distorted bimetallic sites with medium size in Ni5Co5-AC promoted the production of cyclohexanol by hydrogenation of anisole and subsequent cleavage of C6H11O–CH3 bond.

Funder

U.S. Department of Energy

Washington State University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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